Complete disassembly of carbon disulfide by a ditantalum complex.
نویسندگان
چکیده
The side-on end-on dinitrogen complex [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-H)(2)(μ-η(2):η(1)-N(2)) reacts with CS(2) with complete cleavage of both C=S double bonds and the formation of [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-S)(2)(μ-CH(2)), which has two bridging sulfides and a bridging methylene unit. Further reaction with H(2) produces CH(4) and the disulfide complex.
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ورودعنوان ژورنال:
- Chemical communications
دوره 46 46 شماره
صفحات -
تاریخ انتشار 2010